Zheng, Jian published the artcileDifluorocarbene-Derived Trifluoromethylthiolation and [18F]Trifluoromethylthiolation of Aliphatic Electrophiles, Name: (4-(Bromomethyl)phenyl)(trifluoromethyl)sulfane, the publication is Angewandte Chemie, International Edition (2015), 54(45), 13236-13240, database is CAplus and MEDLINE.
The first trifluoromethylthiolation and [18F]trifluoromethylthiolation of alkyl electrophiles with in situ generated difluorocarbene in the presence of elemental sulfur and external (radioactive) fluoride ion is described. This transition-metal-free approach is high yielding, compatible with a variety of functional groups, and operated under mild reaction conditions. The conceptual advantage of this exogenous-fluoride-mediated transformation enables unprecedented syntheses of [18F]CF3S-labeled mols. from most commonly used [18F]fluoride ions. The rapid radiochem. reaction time (≤1 min) and high functional-group tolerance allow access to a variety of aliphatic [18F]CF3S compounds in high yields.
Angewandte Chemie, International Edition published new progress about 21101-63-3. 21101-63-3 belongs to bromides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Bromide,sulfides,Benzyl bromide,Benzene, name is (4-(Bromomethyl)phenyl)(trifluoromethyl)sulfane, and the molecular formula is C10H10O2, Name: (4-(Bromomethyl)phenyl)(trifluoromethyl)sulfane.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary