Norrild, Jens Chr. published the artcileDesign, synthesis and structure of new potential electrochemically active boronic acid-based glucose sensors, Computed Properties of 166821-88-1, the publication is Journal of the Chemical Society, Perkin Transactions 2 (2002), 303-311, database is CAplus.
In the authors’ studies on new boronic acid based carbohydrate sensors three new boronic acids (2-FcCH2NMeCH2C6H4B(OH)2 (3), 1,2-(2-(HO)2BC6H4CH2NMeCH2)2ferrocene (7) and 1,1′-(2-(HO)2BC6H4CH2NMeCH2)2ferrocene (11)) containing a ferrocene moiety were synthesized. Their design includes an intramol. B-N bonding motif to facilitate binding at physiol. pH. The authors report the synthesis of the compounds and studies on glucose complexation as studied by 13C NMR spectroscopy. The crystal structure of 2,4,6-tris[2-(N-ferrocenylmethyl-N-methylaminomethyl)phenyl]boroxin (13) (boroxin of boronic acid 3) (boroxin = cyclotriboroxane) was obtained and compared with structures obtained of 2,4,6-tris[2-(N,N-dimethylaminomethyl)phenyl]boroxin (14) and 2-(2-(dimethylaminomethyl)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane (15). The structure of 13 shows the existence of intramol. B-N bonds in the solid phase.
Journal of the Chemical Society, Perkin Transactions 2 published new progress about 166821-88-1. 166821-88-1 belongs to bromides-buliding-blocks, auxiliary class Bromide,Boronic acid and ester,Benzyl bromide,Benzene,Boronic Acids,Boronic acid and ester, name is 2-(2-(Bromomethyl)phenyl)-5,5-dimethyl-1,3,2-dioxaborinane, and the molecular formula is C12H16BBrO2, Computed Properties of 166821-88-1.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary