Koelle, U.’s team published research in Journal of Organometallic Chemistry in 233 | CAS: 18346-57-1

Journal of Organometallic Chemistry published new progress about 18346-57-1. 18346-57-1 belongs to bromides-buliding-blocks, auxiliary class Cobalt, name is Cobalt(II) dibromo(1,2-dimethoxyethane), and the molecular formula is C4H10Br2CoO2, Computed Properties of 18346-57-1.

Koelle, U. published the artcileCpCoBr intermediates in the cyclopentadienylation of CoBr2 with sodium cyclopentadienide, Computed Properties of 18346-57-1, the publication is Journal of Organometallic Chemistry (1982), 233(2), 253-8, database is CAplus.

Reaction of CoBr2 and NaCp (Cp = η5-cyclopentadienyl) at low temperature, followed by addition of diene or acetylene gives the complexes CpCo(diene). The scope and mechanism of this novel reaction were investigated. The intermediate is [CpCoBr]2. Further reaction of Cp2Co and CoBr2 gives [CoCp2]Br and Co, the amounts of which vary with the reaction time.

Journal of Organometallic Chemistry published new progress about 18346-57-1. 18346-57-1 belongs to bromides-buliding-blocks, auxiliary class Cobalt, name is Cobalt(II) dibromo(1,2-dimethoxyethane), and the molecular formula is C4H10Br2CoO2, Computed Properties of 18346-57-1.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary