Tanner, Dennis D. published the artcileReexamination of the reaction of a “graded set” of radicals with N-bromosuccinimide: a kinetic argument concerning the π, and ω states of succinimidyl, Product Details of C6H12Br2, the publication is Journal of the American Chemical Society (1985), 107(23), 6584-9, database is CAplus.
The NBS [N-bromosuccinimide] of CH2Cl2 with added substrates which yield stable radicals was reinvestigated. The proposal that these substrates would affect the ratio of BrCH2CH2CONCO (BPI)/CHCl2Br, the solvent bromination product, was not substantiated. Bromination of Me2CHCHMe2, cyclohexene, and butadiene by NBS in CH2Cl2 plus H2C:CCl2 gives essentially the same BPI/CHCl2Br ratios as in the presence of neopentane but large yields of brominated and polybrominated products. Similar reactions in the presence of up to 2.5 M C6H6 always yield BPI but also highly brominated benzene derivatives BPI is detected in the NBS bromination of CHCl3 under all conditions and is the major product in the presence of H2C:CCl2 chloride. Photolysis of N-iodosuccinimide-I2 in CHCl3 gives ICH2CH2CONCO as the chief product. None of these observations support the hypothesis of σ and π states of the succinimidyl radical (S·), while the NBS results appear consistent with competing S·-Br· chains.
Journal of the American Chemical Society published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C12H16N2O2, Product Details of C6H12Br2.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary