Rinderhagen, Heiko published the artcileSynthetic applications in radical/radical cationic cascade reactions, COA of Formula: C7H13BrSi, the publication is Chemistry – A European Journal (2004), 10(4), 851-874, database is CAplus and MEDLINE.
Oxidative photoinduced electron transfer (PET) reactions have been performed with various cyclic cyclopropyl(vinyl) silyl ethers bearing an olefinic or acetylenic side chain. The reactions result in bi- to tetracyclic ring systems via a fragmentation-radical/radical cationic addition reaction pathway with well defined ring juncture. The mode of cyclization (endo/exo) can be partially controlled by addition of nucleophiles due to the suppression of radical cationic reaction pathways. Quantum chem. calculation of the cyclization transition states underline the exptl. found selectivities. Addnl. mechanistic studies concerning the saturation step reveal that the final radical is saturated mostly by the solvent and traces of water in the solvent.
Chemistry – A European Journal published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, COA of Formula: C7H13BrSi.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary