Herberich, Gerhard E. published the artcileDerivatives of borole. V. Synthesis of [1-(diisopropylamino)borole]metal complexes and the Diels-Alder dimer of 1-(diisopropylamino)borole, Category: bromides-buliding-blocks, the publication is Chemische Berichte (1985), 118(11), 4303-13, database is CAplus.
Oxidation of Li [1-(diisopropylamino)borolenediide] (I) with SnCl2 forms the Diels-Alder dimer II. I is a versatile reagent for the formation of [1-(diisopropylamino)borole]metal complexes. Suitable substrates are metal halides (CoBr3·DME, NiCl2·DME), organometallic metal halides, and simple metal halides in the presence of CO. Thermal reactions of II with carbonyl compounds may also give borole complexes. Fifteen compounds of Cr, Mn, Fe, Co, Ni, Ru, and Rh, including triple-decked complexes, are described.
Chemische Berichte published new progress about 18346-57-1. 18346-57-1 belongs to bromides-buliding-blocks, auxiliary class Cobalt, name is Cobalt(II) dibromo(1,2-dimethoxyethane), and the molecular formula is C4H10Br2CoO2, Category: bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary