Song, Bingrui’s team published research in Advanced Synthesis & Catalysis in 353 | CAS: 25753-84-8

Advanced Synthesis & Catalysis published new progress about 25753-84-8. 25753-84-8 belongs to bromides-buliding-blocks, auxiliary class Copper, name is Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I), and the molecular formula is C10H14O, Name: Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I).

Song, Bingrui published the artcilePalladium/Copper-Catalyzed Di-α-arylation of Acetic Acid Esters, Name: Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I), the publication is Advanced Synthesis & Catalysis (2011), 353(10), 1688-1694, database is CAplus.

A bimetallic palladium/copper catalyst system was found to effectively promote the diarylation of alkyl acetates with aryl halides under unprecedentedly mild conditions. The phenanthroline-copper-phosphine catalyst stabilizes the enolate intermediate to the extent that the deprotonation of esters can be achieved even with the mild base potassium phosphate. The palladium tri-tert-butylphosphine co-catalyst mediates the coupling of the resulting copper enolate with a wide variety of aryl halides with selective formation of the corresponding diarylacetic acid esters.

Advanced Synthesis & Catalysis published new progress about 25753-84-8. 25753-84-8 belongs to bromides-buliding-blocks, auxiliary class Copper, name is Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I), and the molecular formula is C10H14O, Name: Bromo(1,10-phenanthroline)(triphenylphosphine)copper(I).

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary