Hadei, Niloufar’s team published research in Organic Letters in 7 | CAS: 69361-41-7

Organic Letters published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, SDS of cas: 69361-41-7.

Hadei, Niloufar published the artcileThe First Negishi Cross-Coupling Reaction of Two Alkyl Centers Utilizing a Pd-N-Heterocyclic Carbene (NHC) Catalyst, SDS of cas: 69361-41-7, the publication is Organic Letters (2005), 7(17), 3805-3807, database is CAplus and MEDLINE.

The development of an NHC-based system capable of cross-coupling sp3-sp3 centers in high yield has been a long-standing challenge. This communication describes the use of a Pd-NHC catalytic system that achieves room-temperature Negishi cross-couplings of unactivated, primary bromides and alkyl organozinc reagents with a variety of functionality. E.g., alkyl-alkyl Negishi cross-coupling of PhCH2CH2CH2Br and BuZnBr in presence of Pd2(dba)3 and 1,3-bis(2,6-diisopropylphenyl)imidazolium chloride gave up to 75% heptylbenzene.

Organic Letters published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, SDS of cas: 69361-41-7.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary