Yasu, Yusuke published the artcileSunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+, Synthetic Route of 594-81-0, the publication is Chemical Communications (Cambridge, United Kingdom) (2012), 48(43), 5355-5357, database is CAplus and MEDLINE.
A photosensitizer [Ru(bpy)3]2+ catalyzes oxidative coupling reaction of enamines with silyl enol ethers under visible light irradiation by a Xe lamp or sunlight to produce γ-diketones. A 2e-oxidation process involved in this reaction is achieved by a combination of the photoexcited [Ru(bpy)3]2+ species and duroquinone, a 2e-acceptor.
Chemical Communications (Cambridge, United Kingdom) published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C65H82N2O18S2, Synthetic Route of 594-81-0.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary