Sankhla, Rekha published the artcileCorrelation analysis of reactivity in the oxidation of substituted benzylamines by benzyltrimethylammonium tribromide, Product Details of C10H16Br3N, the publication is Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry (2002), 41A(3), 541-546, database is CAplus.
The oxidation of benzylamine and twenty-seven ortho-, meta- and para-monosubstituted benzylamines by benzyltrimethylammonium tribromide (BTMAB), in dimethylsulfoxide (DMSO), gives corresponding aldimines. The reaction is first order with respect to both BTMAB and the amine. The oxidation of deuterated benzylamine exhibited a substantial kinetic isotope effect. Addition of benzyltrimethylammonium bromide does not affect the rate. Tribromide ion was postulated as the reactive oxidizing species. The rates of the oxidation of para- and meta-substituted benzylamines showed excellent correlation in terms of both Taft’s dual substituent-parameter and Charton’s triparametric LDR equations, whereas the ortho-substituted compounds exhibited the best correlation with the Charton’s tetraparametric LDRS equation. The oxidation of para-substituted benzylamines is more susceptible to the delocalization effect than is the oxidation of ortho- and meta-substituted compounds, which display a greater dependence on the field effect. The low pos. value of the η suggests an electron-deficient center in the rate-determining transition state with less charge separation A suitable mechanism was proposed.
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Product Details of C10H16Br3N.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary