Saito, Hitoshi published the artcileFacile synthesis of fluorene-based π-conjugated polymers via sequential bromination/direct arylation polycondensation, Safety of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, the publication is Journal of Polymer Science, Part A: Polymer Chemistry (2015), 53(19), 2198-2201, database is CAplus.
The synthesis of fluorene-based p-conjugated polymers via sequential bromination and direct arylation was demonstrated. Bromination of 9,9-dioctylfluorene using BTMA Br3 efficiently proceeded and barely inhibited the following direct arylation polycondensation, successfully giving π-conjugated polymers. This is the first example of the facile synthesis of π-conjugated polymers in a one-pot fashion, without the need for prior preparation and purification of dibrominated aromatic monomers as well as organometallic monomers, and the bromination reaction using BTMA Br3 is also available to other aromatic compounds such as thiophene and carbazole derivatives Therefore, the fundamental step-economical protocol described here should present new insights for the synthesis of π-conjugated semiconducting materials.
Journal of Polymer Science, Part A: Polymer Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Safety of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary