Mehla, Satish K. published the artcileCorrelation analysis of reactivity in the oxidation of substituted benzaldehydes by benzyltrimethylammonium tribromide, Category: bromides-buliding-blocks, the publication is Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (2002), 41B(4), 832-838, database is CAplus.
The oxidation of benzaldehyde and thirty-five monosubstituted benzaldehydes by benzyltrimethylammonium tribromide (BTMAB) in aqueous acetic acid gives the corresponding benzoic acids. The reaction is first order with respect to each the benzaldehyde and BTMAB. The reaction failed to induce the polymerization of acrylonitrile. There is no effect of benzyltrimethylammonium chloride on the reaction rate. The oxidation of [2H]benzaldehyde (PhCDO) indicated the presence of a substantial kinetic isotope effect. The effect of solvent composition indicated that the reaction rate increases with an increase in the polarity of the solvent. The rates of oxidation of meta- and para-substituted benzaldehydes are correlated in terms of Charton’s triparametric LDR equation whereas the oxidation of ortho-substituted benzaldehydes are correlated with tetraparametric LDRS equation. The oxidation of para- substituted benzaldehydes is more susceptible to the delocalization effect than is the oxidation of ortho-and meta-substituted compounds, which display a greater dependence on the field effect. The pos. value of η suggests an electron-deficient reaction center in the rate-determining step. The reaction is subjected to steric hindrance by the ortho-substituents.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Category: bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary