Lu, Wenqing published the artcileIridium(I)-catalyzed deoxgenation of fluoroalkylsulfoxides with dimethyl diazomalonate to access fluoroalkylthioethers, Formula: C8H6BrF3S, the publication is Chinese Chemical Letters (2022), 33(11), 4865-4869, database is CAplus.
A new method for the preparation of trifluoromethylthioethers RSCF3 [R = Ph, 4-BrC6H4, 4-MeOC6H4, etc.]/difluoromethylthioethers RCF2H [R = 4-O2NC6H4, 4-BrC6H4, 3-ClC6H4, etc.] via iridium(I)-catalyzed deoxgenation of fluoroalkylsulfoxides with di-Me diazomalonate was developed. In the reaction system, di-Me diazomalonate was used as reducing reagent and the corresponding fluoroalkylthioethers were produced through oxygen atom transfer from fluoroalkylsulfoxides to diazomalonate. The protocol featuring effective oxygen atom transfer, mild reaction conditions and good functional groups tolerance offered an alternative strategy for the synthesis of fluoroalkylthioethers.
Chinese Chemical Letters published new progress about 21101-63-3. 21101-63-3 belongs to bromides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Bromide,sulfides,Benzyl bromide,Benzene, name is (4-(Bromomethyl)phenyl)(trifluoromethyl)sulfane, and the molecular formula is C8H6BrF3S, Formula: C8H6BrF3S.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary