Goel, Shruti’s team published research in Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry in 35B | CAS: 111865-47-5

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Product Details of C10H16Br3N.

Goel, Shruti published the artcileKinetics and mechanism of oxidation of some α-hydroxy acids by benzyltrimethylammonium tribromide, Product Details of C10H16Br3N, the publication is Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (1996), 35B(11), 1180-1184, database is CAplus.

The oxidation of glycolic acid, lactic acid, 2-hydroxy-2-methylpropanoic acid, mandelic acid and nine monosubstituted mandelic acids by benzyltrimethylammonium tribromide (BTMAB) in 1:1 (volume/volume) acetic acid-water leads to the formation of the corresponding carbonyl compounds The reaction is first order with respect to BTMAB. Michaelis-Menten type kinetics have been observed with respect to the hydroxy acid. The rates of decomposition of the complexes show an excellent correlation with Hammett’s σ values with low neg. reaction constants The oxidation of α-deuteriomandelic acid indicates the absence of a kinetic isotope effect. The reaction shows a substantial solvent isotope effect (k(H2O)/k(D2O) = 3.57 at 313 K). With an increase in the proportion of acetic acid in the solvent mixture of acetic acid and water, the rate decreases. Addition of benzyltrimethylammonium ion has no effect on the reaction rate. The reaction fails to induce the polymerization of acrylonitrile. A suitable mechanism has been proposed.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Product Details of C10H16Br3N.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary