O’Connell, Kathleen M. published the artcileElectron-transfer reactions and associated conformational changes. Electrochemical reduction of some vicinal dibromides, Computed Properties of 594-81-0, the publication is Journal of the American Chemical Society (1983), 105(6), 1473-81, database is CAplus.
The effect of mol. conformation on the electrochem. reduction of derivatives of trans-1,2-dibromocyclohexane and substituted 1,2-dibromoethanes was studied by low-temperature cyclic voltammetry. Reduction via conformations with antiperiplanar Br atoms is preferred, and conformational interconversion prior to electron transfer was observed in trans-1,2-dibromo- (I) and 1,1-dimethyl-trans-3,4-dibromocyclohexane (II), meso– and dl-Ph(CHBr)2Ph (meso– and dl–III), and Br(CMe2)2Br (IV). Digital simulation of the low-temperature voltammetric data provided thermodn. and kinetic information on the conformational interconversion in I, II, III, and IV. The energy barriers to conformational interconversion in meso– and dl-Me(CHBr)2Me (meso– and dl–V) are quite small, and conformational effects in the electrochem. reduction of V could not be detected at -135°. 1-Methyl-cis-3,trans-4- (VI) and –trans-3,cis-4-dibromocyclohexane (VII) and meso– and dl-Me2CH(CHBr)2CHMe2 (meso– and dl–VIII) exist almost entirely in a single conformation. Voltammetric peak potentials of VI, VII, and meso– and dl–VIII reflect the geometry of their principal conformation.
Journal of the American Chemical Society published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, Computed Properties of 594-81-0.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary