Jayasundara, Chathurika R. K. published the artcileMerging Iridium-Catalyzed C-H Borylations with Palladium-Catalyzed Cross-Couplings Using Triorganoindium Reagents, Category: bromides-buliding-blocks, the publication is Journal of Organic Chemistry (2022), 87(1), 751-759, database is CAplus and MEDLINE.
A versatile and efficient method to prepare borylated arenes furnished with alkyl, alkenyl, alkynyl, aryl and heteroaryl functional groups is developed by merging Ir-catalyzed C-H borylations (CHB) with a chemoselective Pd-catalyzed cross-coupling of triorganoindium reagents (Sarandeses-Sestelo coupling) with aryl halides bearing a boronic ester substituent. Using triorganoindium cross-coupling reactions to introduce unsaturated moieties enables the synthesis of borylated arenes that would be difficult to access through the direct application of the CHB methodol. The sequential double catalyzed procedure can be also performed in one vessel.
Journal of Organic Chemistry published new progress about 942069-47-8. 942069-47-8 belongs to bromides-buliding-blocks, auxiliary class Boronic acid and ester,Boronic Acids,Boronate Esters, name is 2-(3-Bromo-4,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, and the molecular formula is C14H20BBrO2, Category: bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary