Erickson, Paul R. published the artcilePhotochemical Formation of Brominated Dioxins and Other Products of Concern from Hydroxylated Polybrominated Diphenyl Ethers (OH-PBDEs), Safety of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, the publication is Environmental Science & Technology (2012), 46(15), 8174-8180, database is CAplus and MEDLINE.
The photochem. conversion of selected hydroxylated polybrominated di-Ph ethers (OH-PBDEs) to dioxins and other products was investigated. OH-PBDEs, which are both transformation products of polybrominated di-Ph ethers and naturally occurring compounds, undergo direct photolysis to yield a number of products that may have a higher toxicity than their parent. The compounds investigated were 6-OH-PBDE 99, 6′-OH-PBDE 100, and 6′-OH-PBDE 118. Of special interest was 6′-OH-PBDE 118, a potential transformation product of PBDE 153 that is capable of photochem. generating 2,3,7,8-tetrabromodibenzo-p-dioxin, the most toxic brominated dioxin congener. Photolysis experiments were conducted at two different pH values to assess the photochem. behavior of both the phenol and phenolate form of the compounds The percent conversion to dioxin and other photoproducts was determined and the natural product, 6-OH-PBDE 99, was found to have the highest conversion to dioxin (7%). The reaction quantum yields ranged from 0.027 to 0.16 across all photolysis conditions. In addition, it is shown that all three compounds are capable of photochem. generating other compounds of concern, including brominated phenols and a dibenzofuran.
Environmental Science & Technology published new progress about 111865-47-5. 111865-47-5 belongs to bromides-buliding-blocks, auxiliary class Benzenes, name is Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide, and the molecular formula is C10H16Br3N, Safety of Mono(N,N,N-trimethyl-1-phenylmethanaminium) tribromide.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary