Extension of Light-Harvesting Area of Bulk-Heterojunction Solar Cells by Cosensitization with Ring-Expanded Metallophthalocyanines Fused with Fluorene Skeletons was written by Yamamoto, Satoshi;Kimura, Mutsumi. And the article was included in ACS Applied Materials & Interfaces in 2013.Application of 858843-50-2 The following contents are mentioned in the article:
Three near-IR absorbing zinc fluorenocyanine complexes were designed and synthesized as a co-sensitizer for bulk-heterojunction solar cells. Fusing fluorene rings with the porphyrazine rings resulted in narrower band gap and stabilization of both the HOMO and LUMO energy levels compared with a zinc phthalocyanine complex. The synthesized fluorenocyanines were incorporated into bulk-heterojunction solar cells based on regioregular poly(3-hexylthiophene) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61. The addition of zinc fluorenocyanine complex decorated with eight alkyl chains resulted in improved device performance with a 16% enhancement of the short-circuit current compared with that of the reference cell without this zinc fluorenocyanine complex. This study involved multiple reactions and reactants, such as 3,4-Dibromo-2-methylaniline (cas: 858843-50-2Application of 858843-50-2).
3,4-Dibromo-2-methylaniline (cas: 858843-50-2) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. In the pharmaceutical industry organo bromine derivatives are used as sedatives, vasodilators, antiseptic agents, and anticancer agents.Application of 858843-50-2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary