Boga, Carla published the artcileElectron reduction processes of nitrothiophenes. A systematic approach by DFT computations, cyclic voltammetry and E-ESR spectroscopy, Related Products of bromides-buliding-blocks, the publication is Organic & Biomolecular Chemistry (2012), 10(39), 7986-7995, database is CAplus and MEDLINE.
In the framework of the interest in nitrothiophenes as drugs or hits with different pharmacol. applications and considering that in several instances nitroredn. is an essential step for their biol. activity, the authors have studied a complete series of mono-, di-, and tri-nitrothiophenes and by comparison some mononitro benzo[b]thiophenes and benzo[b]furans . Their electroreduction behavior was studied by different techniques: DFT calculations, cyclic voltammetry and electrochem. ESR spectroscopy. Although, the first reduction process for all of the compounds leads to the relevant radical anions, both the computational and there are significant differences in the fate of their corresponding forthcoming reductions, for example, formation of secondary radicals (open-shell electronic structures) or dianions. The effect of the relative positions of the nitro groups during the reduction also was analyzed and rationalized.
Organic & Biomolecular Chemistry published new progress about 52431-30-8. 52431-30-8 belongs to bromides-buliding-blocks, auxiliary class Liquid Crystal &OLED Materials, name is 2,5-Dibromo-3,4-dinitrothiophene, and the molecular formula is C4Br2N2O4S, Related Products of bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary