Wertjes, William C. published the artcileNickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides, Quality Control of 74317-85-4, the main research area is isoindolinone preparation; haloarylcarboxamide preparation intramol arylation nickel phenanthroline catalyst.
The development of the intramol. arylation of sp3 C-H bonds adjacent to nitrogen using aryl halides is described. Arylation was accomplished using either Ni(COD)2 or 1,10-phenanthroline in substoichiometric amounts, and the reaction conditions were applied to a variety of electronically differentiated benzamide substrates. Preliminary studies suggest a mechanism involving aryl and alkyl radical intermediates.
Organic Letters published new progress about Amidation. 74317-85-4 belongs to class bromides-buliding-blocks, name is 2-Bromo-4-methoxybenzoic acid, and the molecular formula is C8H7BrO3, Quality Control of 74317-85-4.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary