Liu, Hui-Yan published the artcileAssembly of Two Metal-Organic Frameworks Based on Distinct Cobalt Dimeric Building Blocks Induced by Ligand Modification: Gas Adsorption and Magnetic Properties, Related Products of bromides-buliding-blocks, the main research area is cobalt pyridinylbenzoate preparation porosity gas adsorption enthalpy antiferromagnetic exchange; crystal structure cobalt pyridinylbenzoate dimeric building block MOF.
Solvothermal reaction of 3,5-di(pyridin-4-yl)benzoic acid (HDPB) with Co(II) leads to a novel metal-organic framework, [Co2O(DPB)2(DMF)2]·xS (1), which represents a rare reo-type net with trigonal prismatic Co dimer, [Co2O(CO2)2N4] as building blocks to construct a 3-dimensional framework containing three different types of nanoscale M12L12 and M24L12 polyhedron cages. More interestingly, under the same condition, the assembly of 4-methyl-3,5-di(pyridin-4-yl)benzoic acid (HMDPB) with Co(II) facilitates the formation of a cationic framework, [Co2(MDPB)3(DMF)](NO3)·xS (2), with Co dimer, [Co2(CO2)3N4], as building blocks. Complex 2 represents the 1st example of a zeolite-like network with 48-nuclear SOD cage. The significant effect of subtle modification of ligand on the overall MOFs is discussed. Also, the gas adsorption studies reveal that 1 exhibits permanent porosity and selective CO2 uptake. Variable-temperature magnetic susceptibility measurements show that both 1 and 2 exhibit antiferromagnetic behavior.
Inorganic Chemistry published new progress about Adsorption enthalpy, isosteric. 74896-66-5 belongs to class bromides-buliding-blocks, name is Methyl 3,5-dibromo-4-methylbenzoate, and the molecular formula is C9H8Br2O2, Related Products of bromides-buliding-blocks.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary