Zheng, Meifang published the artcileOxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones, Quality Control of 651341-68-3, the main research area is isocoumarin alkanone preparation palladium catalyst oxidative Heck alkenyl alc.
Highly regioselective nucleopalladation for the oxidative coupling of internal alkynes with alkenyl alcs. by using green and low-costing oxygen as the sole oxidant was studied. This one-pot cascade cyclization proceeds through Pd-catalyzed intramol. C-O bond cyclization, insertion of nonbiased alkenyl alcs., -H elimination, and reinsertion of a HPdX species, which is finally transferred to the target ketones. This method has the advantages of mild conditions, good functional group tolerance, and can be performed with unactivated alkenes to afford isocoumarin derivatives
European Journal of Organic Chemistry published new progress about Alkenyl alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 651341-68-3 belongs to class bromides-buliding-blocks, name is Ethyl 2-bromo-4-fluorobenzoate, and the molecular formula is C9H8BrFO2, Quality Control of 651341-68-3.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary