Hebeisen, Paul published the artcileRing opening of cyclic sulfamidates with bromophenyl metal reagents: complementarity of sulfamidates and aziridines, Related Products of bromides-buliding-blocks, the main research area is cyclic sulfamidate preparation aryl iodide derived Grignard ring opening; stereochem inversion regioselective ring opening.
Bromophenyl magnesium reagents generated via a Knochel type magnesium-halogen exchange of aryl iodides undergo regioselective ring opening of cyclic primary and secondary N-Boc sulfamidates in good to excellent yields. With secondary sulfamidates the reaction proceeds with clean inversion of the stereochem. This protocol complements the ring opening of aziridines with bromophenyl metal reagents and extends its scope to secondary substrates.
Tetrahedron Letters published new progress about Amino alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 211315-53-6 belongs to class bromides-buliding-blocks, name is (R)-tert-Butyl (2-(4-bromophenyl)propyl)carbamate, and the molecular formula is C14H20BrNO2, Related Products of bromides-buliding-blocks.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary