《Hydrodebromination of Aromatic Bromides Catalyzed by Unsupported Nanoporous Gold: Heterolytic Cleavage of Hydrogen Molecule》 was written by Zhao, Yuhui; Feng, Xiujuan; Zhang, Sheng; Yamamoto, Yoshinori; Bao, Ming. Recommanded Product: 2675-79-8This research focused onunsupported nanoporous gold catalyst preparation surface structure; aromatic bromide gold catalyst debromination; aryl compound preparation. The article conveys some information:
Unsupported nanoporous gold (AuNPore) was a highly efficient, practically applicable, and recyclable catalyst for hydrodebromination of aromatic bromides. The AuNPore-catalyzed hydrodebromination of aromatic bromides proceeded smoothly at relatively low hydrogen pressure and temperature to achieve good to excellent yields of the corresponding non-bromine variants. The selective hydrodebromination reaction occurred exclusively in the coexistence of chlorine atom. For the first time, a mechanistic study revealed that the H-H bond splits in a heterolysis manner on the surface of AuNPore to generate Au-H hydride species. In the experimental materials used by the author, we found 1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Recommanded Product: 2675-79-8)
1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Recommanded Product: 2675-79-81-Bromo-3,4,5-trimethoxybenzene can be used to synthesize analogs of HA14-1, which shows promising anticancer properties.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary