《Arylsilylation of Electron-Deficient Alkenes via Cooperative Photoredox and Nickel Catalysis》 was published in ACS Catalysis in 2020. These research results belong to Zhang, Zhikun; Hu, Xile. Quality Control of 1-Bromo-4-(trifluoromethyl)benzene The article mentions the following:
Carbosilylation of alkenes can be an efficient approach to the synthesis of organosilicon compounds However, few general methods of carbosilylation are known. Here, we introduce a strategy for arylsilylation of electron-deficient terminal alkenes by combining photoredox-catalyzed silyl radical generation, innate reactivity of silyl radical with alkene, and Ni-catalyzed aryl-alkyl cross-coupling. This cooperative photoredox and nickel catalysis operates under mild conditions. It employs readily available alkenes, aryl bromides, and silane as reagents, and it produces useful synthetic building blocks in a modular manner. The experimental part of the paper was very detailed, including the reaction process of 1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7Quality Control of 1-Bromo-4-(trifluoromethyl)benzene)
1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7) belongs to organobromine compounds.Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides. Quality Control of 1-Bromo-4-(trifluoromethyl)benzene
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary