《Visible-Light-Induced Pd-Catalyzed Radical Strategy for Constructing C-Vinyl Glycosides》 was published in Organic Letters in 2020. These research results belong to Li, Ming; Qiu, Yi-Feng; Wang, Cui-Tian; Li, Xue-Song; Wei, Wan-Xu; Wang, Yu-Zhao; Bao, Qiao-Fei; Ding, Ya-Nan; Shi, Wei-Yu; Liang, Yong-Min. COA of Formula: C13H17BrO9 The article mentions the following:
A novel visible-light-induced palladium-catalyzed Heck reaction for bromine sugars and aryl olefins with high regio- and stereochem. selectivity for the preparation of C-glycosyl styrene is described. This reaction takes place in one step at room temperature by using a simple and readily available starting material. This protocol can be scaled up to a wide range of glycosyl bromide donors and aryl olefin substrates. Mechanistic studies indicate that a radical addition pathway is involved. The results came from multiple reactions, including the reaction of (2R,3R,4S,5S,6S)-2-Bromo-6-(methoxycarbonyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate(cas: 21085-72-3COA of Formula: C13H17BrO9)
(2R,3R,4S,5S,6S)-2-Bromo-6-(methoxycarbonyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate(cas: 21085-72-3) may be used for the synthesis of HMR1098-S-Glucuronide Methyl Ester, a new K-ATP-blocking agent being developed as a drug for prevention of sudden cardiac death.COA of Formula: C13H17BrO9
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary