COA of Formula: C7H4BrF3In 2020 ,《Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki-Miyaura Cross-Coupling Reaction》 appeared in ACS Omega. The author of the article were Ishida, Junya; Nakatsuji, Masato; Nagata, Tatsuki; Kawasaki, Hideya; Suzuki, Takeyuki; Obora, Yasushi. The article conveys some information:
The synthesis of new N,N-dimethylformamide (DMF)-protected palladium nanoparticles (Pd NPs-OAc) employing Pd(OAc)2 (= Pd(OCOCH3)2) as the NP precursor was reported. Pd NPs-OAc were comprehensively characterized by transmission electron microscopy, FT-IR, NMR and XPS to determine the Pd NP size distribution and the coordination state of DMF. Pd NPs-OAc were compared with Pd NPs-Cl, using PdCl2 as the NP precursor. The Suzuki-Miyaura cross-coupling reaction proceeded efficiently in the presence of Pd NPs-OAc and a high catalytic activity was observed with a turnover number of up to 1.5 x 105. Furthermore, the Pd NP-OAc catalysts could be recycled at least five times. The experimental part of the paper was very detailed, including the reaction process of 1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7COA of Formula: C7H4BrF3)
1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. COA of Formula: C7H4BrF3 Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary