Product Details of 586-76-5In 2019 ,《Tetrabutylammonium Iodide-Promoted Acyloxylation-Peroxidation of Alkenes with Carboxylic Acid and tert-Butyl Hydroperoxide》 was published in Synlett. The article was written by Chen, Rongxiang; Chen, Wei; Shen, Yuntao; Wang, Zhan-Yong; Dai, Wei; Wang, Kai-Kai; Liu, Lantao. The article contains the following contents:
An efficient synthesis of tert-Bu peroxides such as RCO2CHR1CH2OOt-Bu [R = 2-naphthyl, 2-thienyl, 4-tert-BuC6H4, etc.; R1 = CO2Me, CO2Et, CO2t-Bu] through TBAI-promoted acyloxylation-peroxidation of alkenes by using a carboxylic acid and tert-Bu hydroperoxide was developed. Simple and com. available TBHP would act as the source of the peroxygen radical. The synthetic utility of this method was enhanced by simple manipulations, easily available starting materials, and a wide substrate scope. In the experiment, the researchers used 4-Bromobenzoic acid(cas: 586-76-5Product Details of 586-76-5)
4-Bromobenzoic acid(cas: 586-76-5) has been used to study the metabolic fate of 2-,3-and 4-bromo benzoic acids in rat hepatocytes incubation using high temperature liquid chromatography. It was used in bromine-specific detection of the metabolites of 2-,3-and 4-bromobenzoic acid in the urine and bile of rats by inductively coupled plasma mass spectrometry.Product Details of 586-76-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary