《Stereospecific Iron-Catalyzed Carbon (sp2)-Carbon (sp2) Cross-Coupling of Aryllithium with Vinyl Halides》 was written by Chen, Peng; Wang, Zhi-Yong; Peng, Xiao-Shui; Wong, Henry N. C.. Product Details of 2635-13-4This research focused onvinyl halide aryllithium prepare iron catalyst diastereoselective cross coupling; styrene preparation. The article conveys some information:
An efficient synthetic protocol involving iron-catalyzed cross-coupling of organolithium compounds with vinyl halides as key coupling partners. More than 30 examples were obtained with moderate to good yields and high stereoselectivities. The practicality of this method was evidenced by a gram-scale synthesis. In addition, a preliminary mechanistic investigation were also performed. In the experimental materials used by the author, we found 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4Product Details of 2635-13-4)
Furthermore, the coupling of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4) with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.Product Details of 2635-13-4
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary