The author of 《Nickel-Catalyzed Transformation of Diazoacetates to Alkyl Radicals Using Alcohol as a Hydrogen Source》 were Zhao, Jingjing; Li, Pan; Xu, Yaohua; Shi, Yixin; Li, Fuwei. And the article was published in Organic Letters in 2019. Name: Benzyl 2-bromoacetate The author mentioned the following in the article:
A nickel-catalyzed transformation of diazoacetates to α-carbonyl methylene radicals has been disclosed in the presence of hyperoxide using ethanol as a hydrogen source and solvent. This strategy is successfully applied in the formation of indolin-2-ones or 1,4-dicarbonyl compounds from acrylamides or enamides in moderate to good yields. These reactions underwent radical addition onto C-C double bonds followed by a cyclization/oxidation or an oxidation/hydrolysis process, resp. The results came from multiple reactions, including the reaction of Benzyl 2-bromoacetate(cas: 5437-45-6Name: Benzyl 2-bromoacetate)
Benzyl 2-bromoacetate(cas: 5437-45-6) belongs to benzyl acetate. Benzyl acetate is an aromatic chemical, usually appearing as a clear liquid with a moderate sweet-jasmine fragrance. This compound appears as a component of some of our fragrance blends.Name: Benzyl 2-bromoacetate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary