《Theoretical and photovoltaic investigations of 1,3,5-triazine-based photosensitizers achieving highly efficient DSSCs》 was written by Zhang, Hai; Zang, Xu-Feng; Hong, Yan-Ping; Chen, Zhen-E.. COA of Formula: C4H2Br2SThis research focused ontriazine based dye sensitized solar cell. The article conveys some information:
By establishing a new push-pull relationship, three novel metal-free organic sensitizers based on A′-π-A framework were synthesized, in which A′ and A represent the auxiliary acceptor (triazine) and the main acceptor (cyanoacrylic acid), resp., coded ZS03, ZS04, and ZS05. In this paper, the mol. structure, photophys. property, electrochem. property, theor. calculation, and photovoltaic property of these three sensitizers are described in detail. The results show that the addnl. acceptor and alkyl chains significantly affect the mol.′s energy level and spatial structure. In terms of photovoltaic characteristics, the ZS03-based device exhibits the best power conversion efficiency (PCE) of 7.11%, corresponding to a short-circuit photocurrent d. (Jsc) of 14.31 mA cm-2, an open-circuit voltage (Voc) of 708 mV, and a fill factor (FF) of 0.723, which is the highest efficiency among the known A′-π-A type dyes. It can be determined that the improvement of PCE is mainly due to the combination of the following two factors: the π-spacer with appropriate length and the alkyl chain with a reasonable layout. In the experimental materials used by the author, we found 2,5-Dibromothiophene(cas: 3141-27-3COA of Formula: C4H2Br2S)
2,5-Dibromothiophene(cas: 3141-27-3) , is mainly used as pharmaceutical intermediate and synthesis intermediate. 2,5-Dibromothiophene polymerizes by debromination with magnesium catalyzed by nickel compounds to form poly(2,5- thienylene) .COA of Formula: C4H2Br2S
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary