《Generation of organozinc reagents from arylsulfonium salts using a nickel catalyst and zinc dust》 was published in Organic Letters in 2020. These research results belong to Yamada, Kodai; Yanagi, Tomoyuki; Yorimitsu, Hideki. Product Details of 2635-13-4 The article mentions the following:
Readily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via the selective cleavage of the sp2-hybridized carbon-sulfur bond to produce salt-free arylzinc triflates under mild conditions. This zincation displays superb chemoselectivity and thus represents a protocol that is complementary or orthogonal to existing methods. The generated arylzinc reagents show both high reactivity and chemoselectivity in palladium-catalyzed and copper-mediated cross-coupling reactions.5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4Product Details of 2635-13-4) was used in this study.
Furthermore, the coupling of 5-Bromobenzo[d][1,3]dioxole(cas: 2635-13-4) with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.Product Details of 2635-13-4
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary