《Zirconium-based metal-organic framework as an efficiently heterogeneous photocatalyst for oxidation of benzyl halides to aldehydes》 was written by Xue, Ping; Huang, Jiming; Lin, Liguang; Li, Rong; Tang, Mi; Wang, Zhengbang. Name: o-BromobenzaldehydeThis research focused onzirconium base metal organic framework catalyst preparation thermal stability; benzyl bromide zirconium catalyst photocatalytic oxidation green chem; benzaldehyde preparation. The article conveys some information:
Herein, for the first time, the zirconium-based metal-organic framework (UiO-66-NH2) was applied as an efficiently heterogeneous photocatalyst for conversion of benzyl halides to corresponding benzaldehydes with high selectivity (about 80%) and conversion (up to 99%) in the presence of oxygen and DMF as solvent. Through a series of experiments and anal., the reaction mechanism was proposed to involve nucleophilic attack of the N-oxide. This study provided a general, environmental and high selective method to prepare benzaldehydes and broadened the application fields of UiO-66-NH2. In the experiment, the researchers used o-Bromobenzaldehyde(cas: 6630-33-7Name: o-Bromobenzaldehyde)
o-Bromobenzaldehyde(cas: 6630-33-7) is used in L-threonine aldolase-catalyzed enantio/diastereoselective aldol reactions.Name: o-BromobenzaldehydeIt is also used in L-threonine aldolase-catalyzed enantio and diastereoselective aldol reactions. Further, it reacts with trichloromethane to prepare 1-(2-bromo-phenyl)-2,2,2-trichloro-ethanol.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary