Wang, Zichen; Fang, Huaquan; Liu, Guixia; Huang, Zheng published their research in Organic Letters in 2021. The article was titled 《Ruthenium-Catalyzed Dual Dehydrogenative Silylation of C(sp3)-H Bonds: Access to Diverse Silicon-Centered Spirocycles》.Computed Properties of C9H11Br The article contains the following contents:
The authors report herein a pincer Ru-catalyzed dual intramol. dehydrogenative silylation of primary C(sp3)-H bonds. The reaction features high efficiency, scalability, and good functional group tolerance, allowing a facile and atom-economical access to structurally diverse Si-centered spirocycles, including unprecedented oxa-spirosilabiindanes and aza-spirosilabiindanes. In the experiment, the researchers used 1-Bromo-2-isopropylbenzene(cas: 7073-94-1Computed Properties of C9H11Br)
1-Bromo-2-isopropylbenzene(cas: 7073-94-1) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. The most pervasive is the naturally produced bromomethane.Computed Properties of C9H11Br
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary