In 2019,Organic Letters included an article by Rocaboy, Ronan; Baudoin, Olivier. Recommanded Product: 6630-33-7. The article was titled 《1,4-Palladium Shift/C(sp3)-H Activation Strategy for the Remote Construction of Five-Membered Rings》. The information in the text is summarized as follows:
1,N-Metal shift is an elegant alternative approach enabling the functionalization of remote C-H bonds from simple precursors. In this work, a novel and simple Pd0-catalyzed domino reaction involving 1,4-palladium shift and C(sp3)-H activation and leading to (fused) five-membered rings is reported. This method allowed access to a broad range of valuable arylidene γ-lactams and indanones and was applied to the formal synthesis of (-)-pyrrolam A. In the experimental materials used by the author, we found o-Bromobenzaldehyde(cas: 6630-33-7Recommanded Product: 6630-33-7)
o-Bromobenzaldehyde(cas: 6630-33-7) is used in L-threonine aldolase-catalyzed enantio/diastereoselective aldol reactions.Recommanded Product: 6630-33-7Synthetic applications of o-Bromobenzaldehyde include: synthesis of aza-fused polycyclic quinolines through copper-catalyzed cascade reaction, preparation of 1-substituted indazoles by CuI-catalyzed coupling with N-aryl hydrazides.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary