《B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes》 was written by Long, Peng-Wei; He, Tao; Oestreich, Martin. Recommanded Product: 1-Bromo-2-isopropylbenzeneThis research focused onvinylcyclopropane hydrosilane Lewis acid hydrosilylation catalyst; alkylsilane preparation. The article conveys some information:
A hydrosilylation of vinylcyclopropanes (VCPs) catalyzed by the strong boron Lewis acid B(C6F5)3 is reported. For the majority of VCPs, little or no ring opening of the cyclopropyl unit is observed Conversely, for VCPs with bulky R groups, such as ortho-substituted aryl rings or branched alkyl residues, ring opening is the exclusive reaction pathway. This finding is explained by the thwarted hydride delivery to a sterically shielded, β-silicon-stabilized cyclopropylcarbinyl cation intermediate. In addition to this study using 1-Bromo-2-isopropylbenzene, there are many other studies that have used 1-Bromo-2-isopropylbenzene(cas: 7073-94-1Recommanded Product: 1-Bromo-2-isopropylbenzene) was used in this study.
1-Bromo-2-isopropylbenzene(cas: 7073-94-1) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals.Recommanded Product: 1-Bromo-2-isopropylbenzene The most pervasive is the naturally produced bromomethane.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary