Electric Literature of C20H20BrPIn 2021 ,《Regio-regular poly(thienylene vinylene)s (rr-PTVs) through acyclic diene metathesis (ADMET) polymerization and the impact of alkyl side-chains on polymer molecular weight and solubility》 appeared in Polymer. The author of the article were Katba-Bader, Yousef M.; Meng, Lingyao; Guan, Chao; Qin, Yang. The article conveys some information:
Poly(thienylene vinylene) (PTV) is one of the prototypical conjugated polymers (CPs) that has received relatively little attention. The insertion of one small double bond between every pair of adjacent thiophene units in PTV structures potentially allow direct functionalization of the thienyl rings, which can fine-tune polymer electronic properties without significantly impact main-chain planarity. However, synthetic methods leading to such tailor-designed PTVs are scarce. In this paper, we report a new synthetic strategy that produces a series of regio-regular (rr) PTVs bearing bromine atoms and different alkyl side-chains on every thiophene unit. The methodol. starts with synthesis of well-defined dimeric monomers that lead to rr-PTVs upon ADMET polymerization The monomers and polymers are fully characterized by NMR and absorption spectroscopy. We found that linear and slightly branched alkyl chains led to precipitation during the polymerization process and thus low apparent mol. weight due to limited polymer solubility, while long-branched and bulky silyl-alkyl ether chains led to PTVs with greater solubility and higher mol. weights After reading the article, we found that the author used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Electric Literature of C20H20BrP)
Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. CatOnium ETPB is also used as catalysts in the synthesis of certain organic compounds.Electric Literature of C20H20BrP
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary