In 2018,Hu, Xiao-Qiang; Hu, Zhiyong; Zhang, Guodong; Sivendran, Nardana; Goossen, Lukas J. published 《Catalytic C-N and C-H Bond Activation: ortho-Allylation of Benzoic Acids with Allyl Amines》.Organic Letters published the findings.Recommanded Product: 76006-33-2 The information in the text is summarized as follows:
A facile insertion of ruthenium into aromatic C-H and allylic C-N bonds are the key steps in a [Ru(p-cymene)Cl2]2-catalyzed ortho-C-H allylation of benzoic acids. This protocol allows drawing on the large pool of allylic amines for state-of-the-art ortho-functionalizations of arenes I (R = 2-Et, 2-F, 3-Me, etc.), turning neutral amines into leaving groups. Concise syntheses of biol. active compounds provide further evidence of the synthetic potential of this methodol. In the experimental materials used by the author, we found 3-Bromo-2-methylbenzoic acid(cas: 76006-33-2Recommanded Product: 76006-33-2)
3-Bromo-2-methylbenzoic acid(cas: 76006-33-2) belongs to organobromine compounds.Organobromine chemicals are produced naturally by an array of biological and other chemical processes in our environment. Recommanded Product: 76006-33-2Some of these compounds are identical to man-made organobromine compounds, such as methyl bromide, bromoform, and bromophenols, but many others are entirely new moleclar entities, often possessing extraordinary and important biological properties.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary