In 2022,Guo, Jiawei; Liu, Song; Pang, Qinjiao; Zhang, Hongyun; Gao, Lu; Chen, Li; Song, Zhenlei published an article in Organic Letters. The title of the article was 《Synthesis of Silacyclohexanones from Divinylsilanes and Allylamines by a Rh-Catalyzed Cyclization》.Product Details of 2675-79-8 The author mentioned the following in the article:
An efficient synthesis of silacyclohexanones bearing a variety of silyl substituents was developed by a [Rh(coe)2Cl]2/PCy3-catalyzed cyclization of divinylsilanes with Jun’s allylamine. The silacyclohexanones can be oxidized with DDQ to give the corresponding silacyclohexadienones, which are further transformed into Si analog of 2-deoxystreptamine or exo-alkylidenesilacyclohexadienes.1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Product Details of 2675-79-8) was used in this study.
1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Product Details of 2675-79-81-Bromo-3,4,5-trimethoxybenzene can be used to synthesize N,N′-diarylated indolo[3,2-b]carbazole derivatives, which can find applications in electrophotography.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary