《Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex》 was written by Zubar, Viktoriia; Borghs, Jannik C.; Rueping, Magnus. Name: Bromopentacarbonylmanganese(I) And the article was included in Organic Letters in 2020. The article conveys some information:
A highly chemoselective base-metal catalyzed hydrogenation and acceptorless dehydrogenation of N-heterocycles was presented. A well-defined Mn-complex was operated at low catalyst loading (as low as 2 mol%) and under mild reaction conditions. The described catalytic system tolerated various functional groups and the corresponding reduced heterocycles was obtained in high yields. Exptl. studies indicated a metal ligand cooperative catalysis mechanism. The experimental process involved the reaction of Bromopentacarbonylmanganese(I)(cas: 14516-54-2Name: Bromopentacarbonylmanganese(I))
Bromopentacarbonylmanganese(I)(cas: 14516-54-2) has many other uses. It is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.Name: Bromopentacarbonylmanganese(I)
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary