《Palladium-catalyzed C(sp3)-P(III) bond formation reaction with acylphosphines as phosphorus source》 was written by Zhang, Mengyue; Ma, Zhichao; Du, Hongguang; Wang, Zhiqian. Computed Properties of C4H7Br And the article was included in Tetrahedron Letters in 2020. The article conveys some information:
Pd-catalyzed C(sp3)-P(III) bond formation reaction for alkyl substituted phosphines preparation was developed. In this reaction, various alkyl bromides and limited alkyl chlorides reacted with acylphosphine under relative mild and easily accessible condition, and differential phosphines were afforded in good yields. This reaction made up the application of Pd catalysis in C(sp3)-P(III) bond formation, and indicated a practical application of acylphosphine as a phosphination reagent. In the experiment, the researchers used (Bromomethyl)cyclopropane(cas: 7051-34-5Computed Properties of C4H7Br)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Computed Properties of C4H7Br
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary