Recommanded Product: o-BromobenzaldehydeIn 2019 ,《A nanostructured organic-inorganic hybrid material: Preparation, characterization and catalytic performance for the synthesis of N,N’-alkylidene bisamides》 was published in ChemistrySelect. The article was written by Zare, Abdolkarim; Khanivar, Roghayyeh; Irannejad-Gheshlaghchaei, Navid; Beyzavi, M. Hassan. The article contains the following contents:
A novel nanostructured mesoporous organic-inorganic hybrid material, based on dicationic ionic liquid – anchored with silica, namely nano-2-[N’,N’-dimethyl-N’-(silica-n-propyl)ethanaminium chloride]-N,N-dimethylaminium bisulfate {nano-[DSPECDA][HSO4]}, was prepared and characterized by FT-IR, energy-dispersive X-ray spectroscopy, field emission SEM, X-ray diffraction, thermal gravimetry, differential thermal gravimetric, DTA and adsorption/desorption porosimetry (BET, Langmuir, adsorption/desorption isotherm, BJH and t-plot) methods. Thereafter, the nanomaterial was utilized as a highly effectual, heterogeneous and recyclable nanocatalyst for the synthesis of N,N’-alkylidene bisamides RCONHCH(Ar)NHCOR [R = Me, Ph, Ar = Ph, 4-MeC6H4, 2-BrC6H4, 4-O2NC6H4, etc.] via the condensation reaction of benzaldehydes (1 equivalent) with primary amides (2 equivalent) under solvent-free conditions. The reaction results were better compared with the literature in terms of two or more of these factors: turnover frequency (TOF), yield, temperature, time and the reaction media. The experimental process involved the reaction of o-Bromobenzaldehyde(cas: 6630-33-7Recommanded Product: o-Bromobenzaldehyde)
o-Bromobenzaldehyde(cas: 6630-33-7) is used in L-threonine aldolase-catalyzed enantio/diastereoselective aldol reactions.Recommanded Product: o-BromobenzaldehydeIt is also used in L-threonine aldolase-catalyzed enantio and diastereoselective aldol reactions. Further, it reacts with trichloromethane to prepare 1-(2-bromo-phenyl)-2,2,2-trichloro-ethanol.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary