Product Details of 7073-94-1In 2018 ,《Silylation of Aryl Halides with Monoorganosilanes Activated by Lithium Alkoxide》 was published in Organic Letters. The article was written by Yoshida, Takumi; Ilies, Laurean; Nakamura, Eiichi. The article contains the following contents:
Li alkoxide activates a monoorganosilane to generate a transient LiH/alkoxysilane complex, which quickly reacts with aryl and alkenyl halides at 25° to deliver a diorganosilane product. Exptl. and theor. studies suggest that the reaction includes nucleophilic attack of LiH on the halogen atom of the organic halide to generate a transient organolithium/alkoxysilane intermediate, which undergoes quick C-Si bond formation within the complex. In the experimental materials used by the author, we found 1-Bromo-2-isopropylbenzene(cas: 7073-94-1Product Details of 7073-94-1)
1-Bromo-2-isopropylbenzene(cas: 7073-94-1) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Product Details of 7073-94-1
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary