Ydhyam, Sridhar; Cha, Jin Kun published their research in Organic Letters on December 4 ,2015. The article was titled 《Construction of Seven-Membered Carbocycles via Cyclopropanols》.Synthetic Route of C11H13BrO2 The article contains the following contents:
A new method for seven-membered ring annulation has been devised by an intramol. cross-coupling of cyclopropanols and aryl/alkenyl halides. This cyclization reaction is broad in scope and provides easy access to not only fused but also bridged bicyclic compounds In the part of experimental materials, we found many familiar compounds, such as Ethyl 3-(2-bromophenyl)propanoate(cas: 135613-33-1Synthetic Route of C11H13BrO2)
Ethyl 3-(2-bromophenyl)propanoate(cas: 135613-33-1) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. Synthetic Route of C11H13BrO2 The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary