《1,2-Dibromoethane and KI mediated α-acyloxylation of ketones with carboxylic acids》 was written by Wang, Xujie; Li, Gangsheng; Yang, Yanan; Jiang, Jianshuang; Feng, Ziming; Zhang, Peicheng. Quality Control of 4-Bromobenzoic acid And the article was included in Chinese Chemical Letters in 2020. The article conveys some information:
The 1,2-dibromoethane- and KI-mediated α-acyloxylation of ketones is reported in moderate to good yield without the use of transition metals and strong oxidants. Various acids are well tolerated with wide functional group compatibility. An 1,2-dibromoethane- and KI-catalyzed reaction mechanism is proposed based on the results of control experiments The experimental part of the paper was very detailed, including the reaction process of 4-Bromobenzoic acid(cas: 586-76-5Quality Control of 4-Bromobenzoic acid)
4-Bromobenzoic acid(cas: 586-76-5) has been used to study the metabolic fate of 2-,3-and 4-bromo benzoic acids in rat hepatocytes incubation using high temperature liquid chromatography. It was used in bromine-specific detection of the metabolites of 2-,3-and 4-bromobenzoic acid in the urine and bile of rats by inductively coupled plasma mass spectrometry.Quality Control of 4-Bromobenzoic acid
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary