Sawazaki, Taka; Shimizu, Yusuke; Oisaki, Kounosuke; Sohma, Youhei; Kanai, Motomu published their research in Organic Letters on December 21 ,2018. The article was titled 《Convergent and Functional-Group-Tolerant Synthesis of B-Organo BODIPYs》.Recommanded Product: potassium (3-bromophenyl)trifluoroborate The article contains the following contents:
Boron-dipyrromethenes (BODIPYs) are one of the most important fluorescent materials. Despite their potential unique properties, however, B,B-fluoro-organo BODIPYs (BFR-BODIPYs) possessing an organo group (R) on the boron center have not been studied in detail, due in part to challenges related to their synthesis. In this paper, a convergent synthesis of BFR-BODIPYs operative under mild conditions is reported. Conversions of the thus-synthesized functionalized BFR-BODIPYs by cross-coupling, condensation, and SN2 reactions at the R group are also demonstrated.potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8Recommanded Product: potassium (3-bromophenyl)trifluoroborate) was used in this study.
potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8) belongs to organobromine compounds.Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Recommanded Product: potassium (3-bromophenyl)trifluoroborate Due to the reactivity of bromide, they are used as potential precursors or important intermediates in organic synthesis.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary