《Base-Free Mizoroki-Heck Reaction Catalyzed by Rhodium Complexes》 was written by Martinez, Remi; Voica, Florina; Genet, Jean-Pierre; Darses, Sylvain. Recommanded Product: potassium (3-bromophenyl)trifluoroborate And the article was included in Organic Letters on August 16 ,2007. The article conveys some information:
A base-free rhodium-catalyzed Mizoroki-Heck (M-H) reaction using potassium aryltrifluoroborates as the arylating agent of alkenes and acetone as a green “”oxidant”” is described. E.g., reaction of 4-ClC6H4BF3K and CH2:CH2CO2CMe3 in presence of [Rh(CH2:CH2)Cl]2 gave 71% arylated ester I. Thanks to the ready availability of organoboranes, this reaction should constitute an interesting alternative to conventional M-H reactions using aryl halides. The experimental process involved the reaction of potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8Recommanded Product: potassium (3-bromophenyl)trifluoroborate)
potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution.Recommanded Product: potassium (3-bromophenyl)trifluoroborate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary