Safety of Bromopentacarbonylmanganese(I)In 2020 ,《Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C-C Bond Formation》 appeared in Organometallics. The author of the article were Daw, Prosenjit; Kumar, Amit; Oren, Dror; Espinosa-Jalapa, Noel Angel; Srimani, Dipankar; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Carmieli, Raanan; Ben-David, Yehoshoa; Milstein, David. The article conveys some information:
Acridine-based PNP pincer complexes were previously used for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, the authors report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. The authors also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C-C bond at the C9 position of the acridine ring.Bromopentacarbonylmanganese(I)(cas: 14516-54-2Safety of Bromopentacarbonylmanganese(I)) was used in this study.
Bromopentacarbonylmanganese(I)(cas: 14516-54-2) has many other uses. It is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.Safety of Bromopentacarbonylmanganese(I)
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary