Li, Hanning; Yang, Yang; Jing, Xu; He, Cheng; Duan, Chunying published an article in 2021. The article was titled 《Multi-Component Metal-Organic Frameworks Significantly Boost Visible-Light-Driven Hydrogen Production Coupled with Selective Organic Oxidation》, and you may find the article in Chemistry – An Asian Journal.Recommanded Product: Tris(4-bromophenyl)amine The information in the text is summarized as follows:
Visible-light-driven hydrogen production coupled with selective organic oxidation has attracted increasing attention, as it not only provides clean and renewable energy, but also utilizes the other half reaction to achieve some value-added organic chems. Metal-organic frameworks based on metal clusters and organic ligands self-assembly give a perspective on the formation of multifunctional heterogeneous photocatalyst to significantly boost visible-light photocatalytic activities under mild conditions. By incorporating two types of photoactive units, tricarboxytriphenylamine (H3TCA) and tris(4-(pyridinyl)phenyl)amine (NPy3), into a single metal-organic frameworks, a multi-component MOF Co-MIX was obtained. With the redox active metal centers enabling the photoexcitation reduction of protons into hydrogen and the photogenerated holes promoting considerable oxidation of substrates, the resulting Co-MIX exhibits high catalytic activity for the photocatalytic hydrogen production coupled with selective oxidation of benzylamine or 1,2,3,4-tetrahydroisoquinoline. Importantly, the photocatalytic experiments of single-component Co-TCA and Co-NPy3 verified the pos. synergistic effects on stability and photocatalytic ability of the two ligands (H3TCA and NPy3) in one single MOF, revealing that the multi-component strategy is very important for the efficient charge separation and excellent photocatalytic activity of the catalyst. In the part of experimental materials, we found many familiar compounds, such as Tris(4-bromophenyl)amine(cas: 4316-58-9Recommanded Product: Tris(4-bromophenyl)amine)
In other references, Tris(4-bromophenyl)amine(cas: 4316-58-9) is often used in the synthesis of porous luminescent covalent–organic polymers (COPs)Recommanded Product: Tris(4-bromophenyl)amine
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary