On June 30, 2019, Kawano, Teruhiro; Watari, Ryo; Kayaki, Yoshihito; Ikariya, Takao published an article.Name: 2-(2-Bromoethyl)isoindoline-1,3-dione The title of the article was Catalytic Hydrogenation of Carboxamides with a Bifunctional Cp*Ru Catalyst Bearing an Imidazol-2-ylidene with a Protic Aminoethyl Side Chain. And the article contained the following:
Synthesis of a Cp*Ru complex bearing an NH2-functionalized N-heterocyclic carbene (C-NH) I (R = CH3) was achieved by treatment of Cp*RuBr(isoprene) with an equimolar amount of a silver complex, which was generated from Ag2O and 1-(2-aminoethyl)-3-methylimidazolium bromide, in CH3CN at room temperature The new Cp*RuBr(C-NH) complex I showed a higher catalytic performance than the related Cp*RuCl(P-NH) and Cp*RuCl(N-NH) complexes. In the reaction of N-arylcarboxamides R1C(O)NR2R3 (R1 = H, C6H5, pyridin-3-yl; R2 = R3 = CH3; R2 = H, R3 = C6H5; R2R3 = -C(O)(CH2)3-, etc.), the amine products R2R3NH were obtained in satisfactory yields under mild temperature conditions. The experimental process involved the reaction of 2-(2-Bromoethyl)isoindoline-1,3-dione(cas: 574-98-1).Name: 2-(2-Bromoethyl)isoindoline-1,3-dione
The Article related to amine preparation, carboxamide hydrogenation ruthenium catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Name: 2-(2-Bromoethyl)isoindoline-1,3-dione
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary